Tetrahedron Letters p. 3777 - 3780 (1994)
Update date:2022-08-03
Topics:
Robertson, Jeremy
Burrows, Jeremy N.
The thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity.
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