Chemical Communications p. 3100 - 3102 (2014)
Update date:2022-08-03
Topics:
Beaufils, Damien
Danger, Gregoire
Boiteau, Laurent
Rossi, Jean-Christophe
Pascal, Robert
A stereochemical study of a potentially prebiotic peptide-forming reaction was carried out as the first part of a systems chemistry investigation of potential paths for symmetry breaking. Substantial diastereomeric excesses result from a fast epimerization of the 5(4H)-oxazolone intermediate in aqueous solution. The Royal Society of Chemistry.
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