Journal of Organic Chemistry p. 13854 - 13860 (2018)
Update date:2022-08-02
Topics:
Reddy, Leleti Rajender
Kotturi, Sharadsrikar
Waman, Yogesh
Ravinder Reddy, Vudem
Patel, Chirag
Kobarne, Ajinath
Kuttappan, Sasikumar
A highly efficient method of visible light mediated Ni(II)-catalyzed photoredox N-arylation of Cbz-amines/Boc-amines with aryl electrophiles at room temperature is reported. The methodology provides a common access to a wide variety of N-aromatic and N-heteroaromatic carbamate products that find use in the synthesis of several biologically active molecules and provides a distinct advantage over traditional palladium-catalyzed Buchwald reaction.
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(2018)