Lewis-acid Catalysed Tandem Reaction Diels-Alder- Sigmatropic Shift between Buta-1,3-dienyl Thiocyanic Acid Ester and Acryloyl Chloride: Application in the Synthesis of 2-Azabicyclooct-5-ene Derivatives.

DOI: 10.1039/c39940001001

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1001 - 1002 (1994)

Update date:2022-08-04

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Authors:

Schoepfer, Joseph

Marquis, Christian

Pasquier, Cecile

Neier, Reinhard

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Article abstract of DOI:10.1039/c39940001001

Buta-1,3-dienyl thiocyanic acid ester reacts with acryloyl chloride in presence of Lewis acid catalysts to produce directly the rearranged product of type 3b via a combination of a Diels-Alder reaction with a <3,3> sigmatropic shift; the 1,4-substituted c

Full text of DOI:10.1039/c39940001001

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