Tetrahedron Letters p. 9007 - 9010 (1994)
Update date:2022-08-03
Topics:
Schwink, Lothar
Knochel, Paul
A procedure involving a hydroboration, boron-zinc exchange and asymmetric addition to an aldehyde allows the reductive addition of olefins to aldehydes in 50-96percent ee.A short and efficient 3 step synthesis of ginnol (61percent overall yield, 92percent ee) demonstrates the synthetic utility of the method.
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Doi:10.1021/acs.jmedchem.6b00585
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