Erratum: Synthetic exploitation of halogenated alkenes containing an electron-withdrawing group: Synthesis of α-chlorohydrazones and ketene aminals by regiospecific reactions of in situ generated imide chlorides (Tetrahedron Letters (2014) 55 (2085-2089))

Full text of DOI:10.1016/j.tetlet.2014.05.114

Accepted Manuscript
Corrigendum
Corrigendum to ‘Synthetic exploitation of halogenated alkenes containing an
electron-withdrawing group: synthesis of α-chlorohydrazones and ketene ami-
nals by regiospecific reactions of in situ generated imide chlorides’ [Tetrahedron
Letters 55 (2014) 2085–2089]
Amac Fatih Tuyun
PII:
S0040-4039(14)00945-9
DOI:
http://dx.doi.org/10.1016/j.tetlet.2014.05.114
TETL 44705
Reference:
Tetrahedron Letters
To appear in:
Please cite this article as: Tuyun, A.F., Corrigendum to ‘Synthetic exploitation of halogenated alkenes containing
an electron-withdrawing group: synthesis of α-chlorohydrazones and ketene aminals by regiospecific reactions of
in situ generated imide chlorides’ [Tetrahedron Letters 55 (2014) 2085–2089], Tetrahedron Letters (2014), doi:
http://dx.doi.org/10.1016/j.tetlet.2014.05.114
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Corrigendum
Corrigendum to ‘Synthetic exploitation of halogenated alkenes
containing an electron-withdrawing group: synthesis of α-
chlorohydrazones and ketene aminals by regiospecific reactions
of in situ generated imide chlorides’
[Tetrahedron Letters 55 (2014) 2085–2089]
Amac Fatih Tuyun*
Department of Chemical Engineering, Faculty of Engineering and Architecture,
Beykent University, Sisli-Ayazaga, 34396 Istanbul, Turkey
Reactions of compounds 6 and 7 gave bisaminated substitution products 8 or α-
chlorohydrazones 9, depending on the electronic nature of the substituent R (Scheme
3).
Scheme 3. Synthetic pathways for ketene aminals 8a–e and α-chlorohydrazones 9a–e.
The author deeply regrets that full citation of previous work on this chemistry was not
provided explicitly in the published manuscript text. Next sentence omitted.

Reactions of compound 6 with anilines of type 7 containing electron-withdrawing
groups (EWG) have previously been described in: Zapol’skii, V. A.; Nutz, E.;
Namyslo, J. C.; Adam, A. E. W.; Kaufmann, D. E.; Synthesis; 2006, 2927–2933.
Reactions of compound 6 with anilines of type 7 containing electron-releasing groups
(ERG) have previously been described in: (a) Kaberdin, R. V.; Potkin, V. I.;
Zapol’skii, V. A.; Russ. Chem. Rev.; 1997, 66, 827, and (b) Ol’dekop, Y. A.;
Kaberdin, R. V.; Potkin, V. I.; Shingel, I. A.; J. Org. Chem. USSR (Engl. Transl.);
1979, 15, 39.
Additionally, the reaction scheme in Scheme 4 was directly copied from: Zapol’skii,
V. A.; Nutz, E.; Namyslo, J. C.; Adam, A. E. W.; Kaufmann, D. E.; Synthesis; 2006,
2927–2933.
The authors would like to apologise for any inconvenience caused.
____________________________
DOI of original article: 10.1016/j.tetlet.2014.02.038
Dr. Amac Fatih Tuyun
Department of Chemical Engineering
Beykent University
Sisli-Ayazaga
Istanbul
34396
Turkey
aftuyun@gmail.com;aftuyun@beykent.edu.tr