Welcome to LookChem.com Sign In|Join Free

Article Doi

Facile Synthesis of Four-membered Ring Platinalactam Complexes and the Single-crystal Structure of (cod=cycloocta-1,5-diene)

DOI: 10.1039/DT9940001831

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1831 - 1836 (1994)

Update date:2022-08-04

Topics:

Authors:

Henderson, WilliamHenderson, William

Nicholson, Brian K.Nicholson, Brian K.

Oliver, Allen G.Oliver, Allen G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940001831

Treatment of the complexes with 1 equivalent of ethyl-N-cyanoacetylcarbamate and an excess of silver(I) oxide in refluxing dichloromethane afforded the new platinalactam complexes <*> (L=PPh3; L2=cod or dppe) in high yield.A single-crystal X-ray diffraction study on the cod derivative confirms the presence of a planar four-membered platinalactam ring system.Molecular parameters and NMR spectroscopic properties of the metallacycles are discussed, in terms of the differing trans influences of the C- and N-donor atoms of the metallacycle.

View More

Products guided by the article

Product name:[Pt(CH(CN)C(O)N(CO2C2H5))((C6H5)2PCH2CH2P(C6H5)2)]

Cas No:158404-40-1

158404-40-1

R&D Labs maybe for 158404-40-1

Relevant to this article

Hot Product