Facile Synthesis of Four-membered Ring Platinalactam Complexes and the Single-crystal Structure of (cod=cycloocta-1,5-diene)

DOI: 10.1039/DT9940001831

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1831 - 1836 (1994)

Update date:2022-08-04

Topics:

Authors:

Henderson, William

Nicholson, Brian K.

Oliver, Allen G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940001831

Treatment of the complexes with 1 equivalent of ethyl-N-cyanoacetylcarbamate and an excess of silver(I) oxide in refluxing dichloromethane afforded the new platinalactam complexes <*> (L=PPh3; L2=cod or dppe) in high yield.A single-crystal X-ray diffraction study on the cod derivative confirms the presence of a planar four-membered platinalactam ring system.Molecular parameters and NMR spectroscopic properties of the metallacycles are discussed, in terms of the differing trans influences of the C- and N-donor atoms of the metallacycle.

Full text of DOI:10.1039/DT9940001831

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Pt(CH(CN)C(O)N(CO₂C₂H₅))((C₆H₅)2PCH₂CH₂P(C₆H₅)2)]

Cas No:158404-40-1

R&D Labs maybe for 158404-40-1

Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
WD Silicone Co., Ltd

Contact:+86-27-87204219, +86-27-87215023

Address:2402, HuiGu Space-time Building, 8 Forest Road, East Lake Hi-Tech Development Zone
Tocopharm Co., Ltd.

Contact:+86-021-6989-5597

Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China
Water Chemical Co.,LTD

Contact:+86-21-6856-1349 523-87676172

Address:No16 . BinJiang Road . Taixing Economy Developing Area .JiangSu Province . China
Nanjing distinctions Medical Technology Co., Ltd.(expird)

Contact:+86-15996203785 13914714059

Address:nanjing,jiangsu , China

Relevant to this article

Doi:10.1007/BF00912474
()
Irreversible enzyme inhibitors. LXXXVI. Hydrophobic bonding to dihydrofolic reductase. 8. Substituted-1-aryl-4,6-diamino-1,2-dihydro-2,2-dimethyl-s-triazines.

Doi:10.1002/jps.2600560616
(1967)
Synthesis of Melodienone and 7-Hydroxy-6-hydromelodienone, two Heptenes from Melodorum Fruticosum.

Doi:10.1016/S0040-4020(01)89589-2
(1994)
Pseudopeptide Inhibitors of Ras Farnesyl-Protein Transferase

Doi:10.1021/jm00032a004
(1994)
Expanding the horizon of intermolecular trapping of in situ generated α-oxo gold carbenes: Efficient oxidative union of allylic sulfides and terminal alkynes via C-C bond formation

Doi:10.1039/c4cc00739e
(2014)
The design and evaluation of an l-dopa–lazabemide prodrug for the treatment of Parkinson’s disease

Doi:10.3390/molecules22122076
(2017)

Article Doi