Cycloaddition Mediated Synthesis and Rearrangement of 16-Functionalised 14α,17α-Etheno-19-norsteroids

DOI: 10.1016/S0040-4020(01)80652-9

Source and publish data:

Tetrahedron p. 6347 - 6362 (1994)

Update date:2022-08-03

Topics:

Authors:

Bull, James R.

Grundler, Claudia

Laurent, Henry

Bohlmann, Rolf

Mueller-Fahrnow, Anke

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Article abstract of DOI:10.1016/S0040-4020(01)80652-9

Estra-1,3,5(10),14,16-pentaen-17-yl acetates (1) undergo cycloaddition with 2-acetoxyacrylonitrile to give the corresponding 16α,17β-diacetoxy 14α,17α-etheno 16β-carbonitriles (3), accompanied by minor regio- and stereoisomers depending upon reaction cond

Full text of DOI:10.1016/S0040-4020(01)80652-9

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