Mechanistic and stereochemical studies on Ferrier reaction by means of chirally deuterated glucose

DOI: 10.1016/S0040-4020(01)86708-9

Source and publish data:

Tetrahedron p. 4125 - 4136 (1994)

Update date:2022-07-29

Topics:

Authors:

Yamauchi, Noriaki

Terachi, Takumi

Eguchi, Tadashi

Kakinuma, Katsumi

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Article abstract of DOI:10.1016/S0040-4020(01)86708-9

The mechanism of Ferrier reaction, cyclitol formation from 5-enopyranosides, was investigated by using (E)-selectively deuterated methyl [6-²H]-2,3,4-tri-O-benzyl-α-D-xylo-hex-5-enopyranoside. The overall reaction was non-stereoselective with r

Full text of DOI:10.1016/S0040-4020(01)86708-9

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Product name:methyl (6R)-<6-2H>-2,3,4-tri-O-benzyl-6-O-triphenylmethyl-α-D-glucopyranoside

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