Unexpected Opposite Stereochemistries and Different Mechanisms of Nucleophilic Substitution Reactions of Homochiral tert-Butylphenylthiophosphinoyl Chloride and Bromide

DOI: 10.1039/c39940002223

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2223 - 2224 (1994)

Update date:2022-08-03

Topics:

Authors:

Omelanczuk, Jan

Mikolajczyk, Marian

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940002223

Reactions of ethylmercapto (ethylsulfanyl) anion with homochiral (+)-(S)-tert-butylphenylphosphinochloridothionate 2 and (-)-(S)-tert-butylphenylphosphinobromidothionate 3 proceed with inversion and retention at phosphorus, respectively, as a consequence

Full text of DOI:10.1039/c39940002223

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(+)-(R)-S-ethyl tert-butylphenylphosphinodithioate

Cas No:159684-59-0

R&D Labs maybe for 159684-59-0

Hangzhou Donglou Bio-nutrient Co., Ltd.

Contact:+86-571-82225795,13967112289

Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang
Jiangxi Huashi Pharmaceutical Co., Ltd

Contact:+86-795-4509628

Address:Ningbo Ave., Fengtian Industrial Park, Fengxin Country, Jiangxi, China.
ChangZhou XiaQing Chemical Co., Ltd.

Contact:+86-519-88721665

Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China

Relevant to this article

Synthesis and biological activity of conjugates between paclitaxel and the cell delivery vector penetratin

Doi:10.1016/j.bmcl.2006.02.035
(2006)
Benzopyran-2-one derivatives: Antiinflammatory, analgesic and antiproteolytic agents

Doi:10.1016/0223-5234(94)90034-5
(1994)
Ionic liquid-promoted [3+2]-cycloaddition reactions of nitroformonitrile oxide generated by the cycloreversion of dinitrofuroxan

Doi:10.1016/j.tetlet.2014.02.112
(2014)
A facile and straightforward synthesis of 1,2,3-thiadiazoles from α-enolicdithioesters via nitrosation/reduction/diazotization/cyclization cascade in one-pot

Doi:10.1016/j.tetlet.2014.02.115
(2014)
Synthesis of the pluramycins 2: Total synthesis and structure assignment of saptomycin B

Doi:10.1002/anie.201308017
(2014)
Sialyl Lewis^x analogs based on a quinic acid scaffold as the fucose mimic

Doi:10.1016/j.bmcl.2005.05.004
(2005)

Article Doi