Unexpected Opposite Stereochemistries and Different Mechanisms of Nucleophilic Substitution Reactions of Homochiral tert-Butylphenylthiophosphinoyl Chloride and Bromide

DOI: 10.1039/c39940002223

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2223 - 2224 (1994)

Update date:2022-08-03

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Authors:

Omelanczuk, Jan

Mikolajczyk, Marian

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Article abstract of DOI:10.1039/c39940002223

Reactions of ethylmercapto (ethylsulfanyl) anion with homochiral (+)-(S)-tert-butylphenylphosphinochloridothionate 2 and (-)-(S)-tert-butylphenylphosphinobromidothionate 3 proceed with inversion and retention at phosphorus, respectively, as a consequence

Full text of DOI:10.1039/c39940002223

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