Tetrahedron Asymmetry p. 975 - 980 (1994)
Update date:2022-08-04
Topics:
Sato
Hirokawa
Hattori
Toyota
Kaneko
Addition of molecular fluorine to cis-2-cyclopentene-1,4-diol gave the cis-anti adduct stereoselectively. This meso diol was dissymmetrized by means of acetylation under lipase catalysis to afford the monoacetate with a high enantiomeric purity. Oxidation of the monoacetate followed by elimination of hydrogen fluoride under basic conditions furnished the titled compound which is an attractive building block for chiral fluorinated molecules.
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Doi:10.1016/j.tet.2014.03.020
(2014)Doi:10.1016/S0040-4020(01)82516-3
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(2014)Doi:10.1016/S0040-4039(00)75989-2
(1994)Doi:10.1016/j.tet.2013.10.032
(2014)Doi:10.1039/c9ra09429f
(2020)
