Synthetic Study of Marine Macrolide Swinholide A. Stereocontrolled Synthesis of the C11-C23 Segment

DOI: 10.1016/0040-4039(94)88288-6

Source and publish data:

Tetrahedron Letters p. 8225 - 8228 (1994)

Update date:2022-08-03

Topics: Stereocontrolled Synthesis Synthetic study Swinholide A

Authors:

Nakata, Tadashi

Komatsu, Toshiya

Nagasawa, Kazuo

Yamada, Haruo

Takahashi, Takashi

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Article abstract of DOI:10.1016/0040-4039(94)88288-6

The C11-C23 segment 4 of swinholide A (1) was synthesized stereoselectively starting from (S)-malic acid via double nitroaldol reaction under high pressure and differentiation of the left and right parts of the symmetric compound 10 as the key steps.

Full text of DOI:10.1016/0040-4039(94)88288-6

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