Selectivity in Garratt-Braverman cyclization of aryl-/heteroaryl- substituted unsymmetrical bis-propargyl systems: Formal synthesis of 7′-desmethylkealiiquinone

DOI: 10.1021/jo402749d

Source and publish data:

Journal of Organic Chemistry p. 3789 - 3798 (2014)

Update date:2022-09-26

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Authors:

Das, Joyee

Mukherjee, Raja

Basak, Amit

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Article abstract of DOI:10.1021/jo402749d

Unsymmetrical bis-propargyl ethers and sulfonamides containing various combinations of aryl/heteroaryl substituents at the acetylene termini were synthesized, and their reactivity under basic conditions was studied. Moderate to high (chemo)selectivity was

Full text of DOI:10.1021/jo402749d

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