Chemistry of the β-thiolactones: Substituent and solvent effects on thermal decomposition and comparison with the β-lactones

DOI: 10.1021/jo500577c

Source and publish data:

Journal of Organic Chemistry p. 4068 - 4077 (2014)

Update date:2022-08-05

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Authors:

Noel, Amandine

Delpech, Bernard

Crich, David

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Article abstract of DOI:10.1021/jo500577c

The synthesis of a series of di-, tri-, and tetraalkyl β-thiolactones and β-lactones is described as well as their thermal decomposition with extrusion of carbon oxysulfide and carbon dioxide in two solvents of opposite polarities. The β-thiolactones are

Full text of DOI:10.1021/jo500577c

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