Tetrahedron Letters p. 2327 - 2330 (1993)
Update date:2022-07-30
Topics: Characterization functional group interconversions Biological testing Retrosynthetic analysis Stereochemistry Control Purification and Isolation Ring Formation Protection and Functional Group Manipulation Assembly of Fragments Late-Stage Modifications
Tabuchi, Hiroyasu
Hamamoto, Taisuke
Miki, Shokyo
Tejima, Tsuyoshi
Ichihara, Akitami
A total synthesis of alternaric acid (1) has been achieved.Key reactions include the Julia olefination of tertiary aldehyde 4 and phenylsulfone 5, and novel one-pot construction of 3-acyl-4-hydroxy-5,6-dihydropyrone via Fries type rearrangement of O-enola
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