Trans-hexahydrobenzoxazolidinones in the enantioselective synthesis of β2-amino acids containing proteinogenic side chains

DOI: 10.1002/ejoc.201301834

Source and publish data:

European Journal of Organic Chemistry p. 2275 - 2283 (2014)

Update date:2022-08-03

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Authors:

Bandala, Yamir

Reyes-Rangel, Gloria

Obregon-Zuniga, Arturo

Cruz-Hernandez, Carlos

Corzo, Gerardo

Juaristi, Eusebio

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Article abstract of DOI:10.1002/ejoc.201301834

The use of enantiopure trans-hexahydrobenzoxazolidinones as chiral auxiliaries in the enantioselective synthesis of two β²-amino acids containing proteinogenic side chains (β²-hPhenylalanine and β²-hLysine), in both enantiomeric forms, is described. Absolute configurations were assigned on the basis of X-ray diffraction analysis and chemical correlation methods.

Full text of DOI:10.1002/ejoc.201301834

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