Tetrahedron p. 13485 - 13492 (1994)
Update date:2022-08-05
Topics: Building blocks Synthetically useful C-4 fluorinated
Arnone, Alberto
Bravo, Pierfrancesco
Frigerio, Massimo
Salani, Giuliana
Viani, Fiorenza
The synthesis of 2-fluoromethyl-2-hydroxymethyl-, 2-(dimethoxy)methyl-2-fluoromethyl-, and 2-carboxy-2-fluoromethyl oxiranes 5, 7, and 8 through reaction of diazomethane with β-keto-γ-fluorosubstituted sulphoxide 1 followed by Pummerer rearrangement are s
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