Synthesis p. 901 - 903 (1994)
Update date:2022-07-30
Topics:
Ogibin
Starostin
Aleksandrov
Pivnitsky
Nikishin
Two short and simple synthetic routes to the prostaglandin synthons 2-(6-carboxyhexyl)- and 2-(6-methoxycarbonylhexyl)cyclopent-2-en-1-one have been developed. The first is based on a cyclohexanone oxidative transformation with hydrogen peroxide and di-tert-butyl peroxide, the second on the free radical addition reaction of methyl 9-oxononanoate to acrylaldehyde diacylal.
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Doi:10.1016/j.jorganchem.2013.11.026
(2014)Doi:10.1016/j.tet.2014.03.083
(2014)Doi:10.1021/acs.joc.6b00925
(2016)Doi:10.1016/S0040-4039(00)78252-9
(1994)Doi:10.1016/j.crci.2013.08.011
(2014)Doi:10.1039/c8ob02226g
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