Journal of Organic Chemistry p. 4165 - 4178 (2019)
Update date:2022-07-29
Topics:
Qiu, Yi-Feng
Niu, Yue-Jie
Wei, Xi
Cao, Bao-Qian
Wang, Xi-Cun
Quan, Zheng-Jun
A AgSCF3/Na2S2O8-promoted trifluoromethylthiolation/cascade cyclization of o-propargyl arylazides (or o-alkynyl benzylazides) triggered by a carbon-carbon triple bond is reported. This strategy provides the synthesis of valuable SCF3-substituted quinoline and isoquinoline systems via the construction of one C(sp2)-SCF3 bond and one C-N bond within one process.
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