Cycloaddition-Oxidative Cleavage Pathways to 14β-Formyl-19-norsteroids

DOI: 10.1016/0040-4039(94)88107-3

Source and publish data:

Tetrahedron Letters p. 6171 - 6174 (1994)

Update date:2022-08-04

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Authors:

Bukk, James R.

Hoadley, Clarissa

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Article abstract of DOI:10.1016/0040-4039(94)88107-3

Cycloaddition of 3-methoxyestra-1,3,5(10),14,16-pentaen-17-yl acetate 1 with methyl propionate, followed by chemoselctive modification of the cycloadduct, furnishes intermediates for reduction-oxidative cleavage raection sequences, leading to the 14β-formyl analogue of estrone and related 14β-formyl-19-norsteroids.

Full text of DOI:10.1016/0040-4039(94)88107-3

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