Insertion of ClPPh2 into a Ta-H bond: Synthesis and structure of the first phosphido derivative of tantalocene

DOI: 10.1021/om00007a072

Source and publish data:

Organometallics p. 3588 - 3591 (1995)

Update date:2022-09-26

Topics:

Authors:

Nikonov, Georgii I.

Kuzmina, Ludmila G.

Mountford, Philip

Lemenovskii, Dmitry A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00007a072

Ph₂PCl easily inserts into the Ta-H bond of Cp₂TaH₃ affording an ionic complex [Cp₂TaH₂(HPPh₂)]Cl (4). This species was deprotonated to give the first phosphido-substituted tantalocene complex Cp₂TaH₂PPh₂ (5), which was characterized by NMR spectroscopy and X-ray crystallography. Thermal decomposition of 5 as well as its reaction with HPPh₂ was studied.

Full text of DOI:10.1021/om00007a072

Products guided by the article

Product name:(C₅H₅)2Ta(H)2(HP(C₆H₅)2)⁽¹⁺⁾*Cl^(1-)=[(C₅H₅)2Ta(H)2(HP(C₆H₅)2)]Cl

Cas No:161161-05-3

R&D Labs maybe for 161161-05-3

Shijiazhuang City Xiehe Pharmaceutical Co., Ltd

Contact:+86-311-80817929

Address:Shangzhuang,Shijiazhuang,China
NINGBO YINZHOU PRECISE COLOR CO.,LTD.

Contact:86-574-88139809 86-574-83033159

Address:Qiming Road,Yinzhou,Ningbo,China
Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
zhengzhou Triz Pharma-Tech Co., Ltd

website:http://www.Trizpharma-tech.com

Contact:+86-0371-86597269，53392065

Address:High-tech Industrial Development Zone, Zhengzhou City, NO.7 Holly Street

Relevant to this article

Ir^III pthalocyaninates: Synthesis and poperties of di(halo)phthalocyaninato(1-)-iridium(III) and di(halo)phthalocyaninato(2-)iridate(III)

Doi:10.1002/zaac.19976230147
(1997)
Doi:10.1021/ja01123a019
(1952)
(π-Allyl) palladium complexes with N,N′-diphenylbispidinone derivatives as a new type of chelating nitrogen ligand: Complexation studies, spectroscopic properties, and an X-ray structure of (3,7-diphenyl-1,5-dimethylbispidinone)[(1,3-η ³-propenyl)-palladium] trifluoromethanesulfonate

Doi:10.1021/om9609527
(1997)
Synthesis and binding studies of a new DNA minor groove binder

Doi:10.1071/C97115
(1998)
Synthesis and reactions of 3-C-branched-chain analogues of 3,6-anhydrodeoxynojirimycin

Doi:10.1080/07328309708006509
(1997)
Doi:10.1246/bcsj.40.2135
(1967)

Article Doi