Inorganic Chemistry p. 1634 - 1636 (1964)
Update date:2022-07-30
Topics:
Lindahl, Charles B.
Jolly, William L.
Diphosphorus tetrachloride displaces carbon monoxide from nickel carbonyl at 0°. With large excesses of P2Cl4, the P2Cl4 reacts as a monofunctional base to form Ni(CO)2(P2Cl4)2 and probably Ni(CO)(P2Cl4)3 and Ni(P2Cl4)4. With large excesses of nickel carbonyl, the P2Cl4 reacts as a difunctional base to form (CO)3NiP2Cl4Ni(CO)3. With intermediate ratios of P2Cl4 to Ni(CO)4, polymeric compounds containing both mono- and difunctional P2Cl4 groups are formed. In reactions with nickel carbonyl, P2Cl4 is a stronger base than PCl3. Diphosphorus tetrachloride decomposes in the presence of boron tribromide at 0° to form a phosphorus trihalide and a phosphorus subhalide, (PX)x. Halogen exchange occurs as completely as possible; with a sufficient excess of BBr3, the adduct PBr3 · BBr3 forms.
Contact:86-931-8272767
Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
ShangHai BMG Chemical Co., Ltd
Contact:+86-13524845543
Address:Room 602, no 291 sikai road shanghai
Jiaozuo Zhongwen Trading Coporation Limited
Contact:--
Address:East Renmin Road
Shifang Taifeng New Flame Retardant Co., Ltd
Contact:02884721008
Address:tingjiang industrial park, hefeng town
Chengdu D-Innovation Pharmaceutical Co., Ltd
Contact:86-28-85105536
Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
Doi:10.1016/j.bmc.2015.05.005
(2015)Doi:10.1021/jo5008064
(2014)Doi:10.1016/j.ejmech.2014.05.024
(2014)Doi:10.1016/j.tet.2015.04.047
(2015)Doi:10.1039/DT9940003569
(1994)Doi:10.1016/j.saa.2012.06.049
(2012)
