Stereocontrolled Hydroxymethylation of Carbohydrate Imines: Formal Synthesis of Destomic Acid and Lincosamine

DOI: 10.1016/S0957-4166(00)86303-X

Source and publish data:

Tetrahedron Asymmetry p. 2261 - 2264 (1994)

Update date:2022-09-26

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Authors:

Delft, Floris L. van

Kort, Martin de

Marel, Gijs A. van der

Boom, Jacques H. van

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Article abstract of DOI:10.1016/S0957-4166(00)86303-X

Addition of <(dimethylphenylsilyl)methyl>magnesium chloride to 6-benzylimino-6-deoxy-1,2;3,4-di-O-isopropylidene-α-D-galactopyranose mediated by Ce(III)Cl3 or CuI/BF3*Et2O proceeds with complete syn- or anti-diastereoselectivity, respectively, to afford h

Full text of DOI:10.1016/S0957-4166(00)86303-X

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