Unusual Reactivity of a Luminescent Bis-μ-Sulfideo Platinum(II) Dimer with Methylene Chloride. X-Ray Structural Characterization of and (dppy = 2-diphenylphosphinopyridine)

DOI: 10.1039/c39950000267

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 267 - 270 (1995)

Update date:2022-09-26

Topics:

Authors:

Yam, Vivian Wing-Wah

Yeung, Phyllis Kok-Yan

Cheung, Kung-Kai

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Article abstract of DOI:10.1039/c39950000267

Reaction of with NaSH in the presence of triethylamine in MeCN produces a luminescent dimeric complex 1 which is characterized by X-ray crystallography; its unusual reactivity with CH2Cl2 to give novel monomeric 2, identified by both NMR spectroscopy and X-ray crystallography, is described (dppy = 2-diphenylphosphinopyridine).

Full text of DOI:10.1039/c39950000267

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