Synthesis of epoxyferrocenes by the oxidation of acyl- and allyl-substituted ferrocenes with dimethyldioxirane

DOI: 10.1016/0022-328X(95)05231-D

Source and publish data:

Journal of Organometallic Chemistry p. 273 - 278 (1995)

Update date:2022-08-04

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Authors:

Adam, Waldemar

Schuhmann, Rosemarie M.

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Article abstract of DOI:10.1016/0022-328X(95)05231-D

The oxidation of acyl- and allylferrocenes 1 and 2 with dimethyldioxirane as the oxygen transfer agent affords the corresponding epoxides 5 and 6 in fair to good yields.Large excesses of oxidant, high temperatures, and an inert atmosphere (argon) minimize

Full text of DOI:10.1016/0022-328X(95)05231-D

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