Enhancement of diastereoselectivity in the Claisen rearrangement induced by remote stereocenters via use of sterically demanding Lewis acid catalysts

DOI: 10.1016/0040-4039(94)02390-W

Source and publish data:

Tetrahedron Letters p. 803 - 806 (1995)

Update date:2022-08-05

Topics:

Authors:

Boeckman Jr., Robert K.

Neeb, Michael J.

Gaul, Micheal D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)02390-W

Several cases of significant enhancement in the diastereoselectivity of acyclic Claisen rearrangement of cyclohexenyl allyl ethers governed principally by remote asymmetric center(s) have been observed when Lewis acid catalysts are employed rather than th

Full text of DOI:10.1016/0040-4039(94)02390-W

Products guided by the article

Product name:(-)-(1S)-4-((E)-5-(tert-butyldiphenylsiloxy)-2-pentenyloxy)-1,5-dimethyl-9-oxo-8-oxabicyclo[4.3.0]nona-4,6-diene

Cas No:161807-13-2

R&D Labs maybe for 161807-13-2

Chengdu Pukang Biotechnology Co., Ltd

Contact:+86-28-82550498

Address:No. 558 Rulin Road,Xinjin county,Chengdu city, China
X.T.Y Environ-Tech Co.,Ltd

Contact:+86-310-7092106

Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
shanghai hekang chemical co.ltd

Contact:021-54173790

Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China
Hawks Chemical

Contact:+44 (0)161 367 9441

Address:

Relevant to this article

Doi:10.1021/jo01016a012
(1965)
From C,N- and N,N-chelated chloroboranes to substituted 1H-2,1-benzazaboroles and 1H-pyrrolo[1,2-c][1,3,2]diazaborolidines: A straightforward route to five-membered rings containing the B-N or N-B-N moiety

Doi:10.1039/c4dt01445f
(2014)
Base-induced self-assembly for one-dimensional coordination polymers via chiral pendant-armed schiff base mononuclear Pb(II) macrocycles

Doi:10.1021/ic5008846
(2014)
Synthesis and in vitro evaluation of 4-trichloromethylpyrrolo[1,2-A] quinoxalines as new antiplasmodial agents

Doi:10.1016/j.ejmech.2014.06.014
(2014)
Novel 5-arylcarbamoyl-2-methylisoxazolidin-3-yl-3-phosphonates as nucleotide analogues

Doi:10.1080/15257770.2014.909046
(2014)
Synthesis of 3,3-disubstituted-2,3-dihydroazanaphthoquinones via simultaneous alkyne oxidation and nitrile hydration of ortho- alkynylarenenitriles

Doi:10.1039/c4ob00852a
(2014)

Article Doi