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Enhancement of diastereoselectivity in the Claisen rearrangement induced by remote stereocenters via use of sterically demanding Lewis acid catalysts

DOI: 10.1016/0040-4039(94)02390-W

Source and publish data:

Tetrahedron Letters p. 803 - 806 (1995)

Update date:2022-08-05

Topics:

Authors:

Boeckman Jr., Robert K.Boeckman Jr., Robert K.

Neeb, Michael J.Neeb, Michael J.

Gaul, Micheal D.Gaul, Micheal D.

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Article abstract of DOI:10.1016/0040-4039(94)02390-W

Several cases of significant enhancement in the diastereoselectivity of acyclic Claisen rearrangement of cyclohexenyl allyl ethers governed principally by remote asymmetric center(s) have been observed when Lewis acid catalysts are employed rather than th

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Full text of DOI:10.1016/0040-4039(94)02390-W

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