Tetrahedron p. 8427 - 8444 (1994)
Update date:2022-07-29
Topics:
Serra, Corine
Dewynter, Georges
Montero, Jean-Louis
Imbach, Jean-Louis
3-C-phosphonosugars were synthetised starting from 2-deoxy-D-ribose and α-D-xylofuranose via the Pudovic rection followed by reduction.Their condensation with nucleobases (thymine and adenine) gave original 3'-C-phosphononucleosides in ribo- and 2-deoxyribo- series, with a stereocontrol of the reactions.Key words: 3-C-phosphonosugar, 3'-C-phosphononucleoside, Pudovic reaction, α-hydroxyphosphonate
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