Acyloin Rearrangement of α-Hydroxy Acetals: Application to the Methyl L-Mycaroside Synthesis

DOI: 10.1016/S0040-4039(00)73311-9

Source and publish data:

Tetrahedron Letters p. 5027 - 5030 (1994)

Update date:2022-08-03

Topics:

Authors:

Sato, Tadashi

Nagata, Tsutomu

Maeda, Kenji

Ohtsuka, Sawako

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Article abstract of DOI:10.1016/S0040-4039(00)73311-9

Acid treatment of α-hydroxy acetals induced 1,2-alkyl, aryl, or alkenyl migration.An alkenyl migration product was utilized as a starting material of methyl L-mycaroside synthesis.

Full text of DOI:10.1016/S0040-4039(00)73311-9

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Product name:3-Benzyloxy-4-methyl-pent-4-en-2-one

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