Stereoselectivite comparee de la reduction de trifluoromethylcetones et des methylcetones correspondantes: nouvelles voies d'acces a des derives trifluoromethyles de pentoses

Article abstract of DOI:10.1016/0040-4020(94)00993-5

The selectivity of the reduction of some trifluoroacetyl-1,3-dioxanes and 1,3-dioxolanes with DIBAH or L-Selectride was studied and compared with that the corresponding methylketones; the results -in accordance with literature- show an important steric hi