Zerovalent palladium and platinum complexes of aminomethylphosphines. Crystal structure of the palladium(0) dibenzylideneacetone complex >

DOI: 10.1016/0022-328X(94)05023-5

Source and publish data:

Journal of Organometallic Chemistry p. 171 - 176 (1995)

Update date:2022-08-04

Topics:

Authors:

Fawcett, John

Kemmitt, Raymond D. W.

Russell, David R.

Serindag, Osman

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)05023-5

Tris(dibenzylideneacetone)dipalladium and bis(dibenzylideneacetone)platinum react with N, N-bis(dicyclohexylphosphinomethyl)methylamine, (Cy2PCH2)2NMe (Cy = cyclohexyl), and with N, N-bis(diphenylphosphinomethyl)methylamine, (Ph2PCH2)2NMe (Ph = phenyl), to give the complexes > (M = Pd or Pt, dba = dibenzylideneacetone), R = Cy or Ph.The zerovalent platinum complex > can be obtained by hydrazine hydrate reduction of a mixture of > and triphenylphosphine or oneof cis- and (Cy2PCH2)2NMe.Thecrystal structure of > has been determined and some reactions of the complexes are reported.Keywords: Palladium; Platinum; Aminomethylphosphines; Dibenzylideneacetone; Crystal structure

Full text of DOI:10.1016/0022-328X(94)05023-5

Products guided by the article

Product name:[Pd(dimethyl acetylenedicarboxylate)(N,N-bis(dicyclohexylphosphinomethyl)methylamine)]

Cas No:163353-96-6

R&D Labs maybe for 163353-96-6

Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
Nanjing Zelang Medical Technology Co. Ltd

Contact:86-25-83063290/13770714480

Address:Ganjiabian 108# 01 Unit,701-702 room,Yao Hua Street,Qixia District,Nanjing,Jiangsu,China
Suns Chemical Sdn Bhd

Contact:0086 371 65711996

Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Shanghai He Yang International Trading Co., Ltd.

Contact:+86-21-52043598

Address:Room 816, Blag.5, No.58 Huachi Road
Zhejiang Sanmei Chemical Industry Co., Ltd

Contact:86-579-87633213

Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.

Relevant to this article

Synthesis and comparative studies of phase transition behaviour of new dimeric liquid crystals consisting of dimethyluracil and biphenyl cores

Doi:10.1016/j.molliq.2016.04.025
(2016)
Room-temperature ortho-alkoxylation and -halogenation of N-tosylbenzamides by using palladium(II)-catalyzed C-H activation

Doi:10.1002/chem.201303923
(2014)
A multidentate ligand based on two triazole groups from click chemistry and its copper(II) and iron(II) complexes: Synthesis, structure, and electrochemistry

Doi:10.1007/s11243-014-9849-2
(2014)
Indole inhibitors of human nonpancreatic secretory phospholipase A₂. 2. Indole-3-acetamides with additional functionality

Doi:10.1021/jm960486n
(1996)
Non-peptide RGD surrogates which mimic a Gly-Asp β-turn: Potent antagonists of platelet glycoprotein IIb-IIIa

Doi:10.1021/jm9701076
(1997)
Synthesis and reactions of N,N-dichloroperfluoroalkanesulfonylamides

Doi:10.1016/0022-1139(93)03034-J
(1994)

Article Doi