Journal of the Chemical Society. Chemical communications p. 145 - 146 (1995)
Update date:2022-08-03
Topics:
Heijden, Harry van der
Hessen, Bart
Thermal α-H abstraction from (C5H4R)2Ti(CH2CMe3)2 (R = H, Me) produces reactive titanocene neopentylidene intermediates under mild conditions, that can either be trapped with PMe3 to yield the alkylidene complexes (C5H4R)2Ti(CHCMe3)PMe3, or add C-H bonds
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