Structural studies of a novel heterocyclic phosphorane

Article abstract of DOI:10.1080/10426509808045499

Reaction of 2,2,6-trimethylthiochroman-3,4-dione with an excess of methylenetriphenyl-phosphorane yields the stabilised ylide (4) by way of an α-ketol rearrangement. X-Ray crystallography indicates that (4) exists as the (Z)-isomer and provides supporting evidence for an enolate structure.

Full text of DOI:10.1080/10426509808045499

Phosphorus, Sulfur, and Silicon and the Related Elements
ISSN: 1042-6507 (Print) 1563-5325 (Online) Journal homepage: http://www.tandfonline.com/loi/gpss20
STRUCTURAL STUDIES OF A NOVEL HETEROCYCLIC
PHOSPHORANE
Christopher D. Gabbutt , John D. Hepworth , B. Mark Heron , Alan M. Jones ,
Eric S. Raper & William Clegg
To cite this article: Christopher D. Gabbutt , John D. Hepworth , B. Mark Heron , Alan M.
Jones , Eric S. Raper & William Clegg (1998) STRUCTURAL STUDIES OF A NOVEL HETEROCYCLIC
PHOSPHORANE, Phosphorus, Sulfur, and Silicon and the Related Elements, 143:1, 221-230,
DOI: 10.1080/10426509808045499
To link to this article: http://dx.doi.org/10.1080/10426509808045499
Published online: 04 Oct 2006.
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Date: 13 June 2016, At: 13:39