Journal of the Chemical Society, Dalton Transactions p. 403 - 408 (1995)
Update date:2022-09-26
Topics:
Beer, Paul D.
Drew, Michael G. B.
Graydon, Andrew R.
Smith, David K.
Stokes, Sally E.
New acyclic monosubstituted aryl cobaltocenium derivatives, functionalised with additional hydrogen-bonding amine groups have been prepared.Quantitative investigation of the anion-binding properties by 1H NMR spectroscopy and electrochemical methods shows enhanced binding believed to be due to amine group participation in hydrogen bonding.Similar recognition studies on 1,1'-bis-substituted aryl cobaltocenium analogues indicate an order of magnitude selectivity for the dihydrogenphosphate anion over simple halide anions.The importance of hydrogen bonding is also illustrated by the first single-crystal structure showing the anion complex of a cobaltocenium recetptor.
website:http://www.fwdchem.com
Contact:86-21-54450828
Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
Contact:+86-22-26358246
Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Yancheng Smiling Imp & Exp Co., Ltd.
Contact:+86-515-83173586
Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Contact:+86-(0)21-3770 9035
Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
Shanghai Demand Chemical Co., ltd，China
Contact:86-021-55237578/55239122
Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China
Doi:10.1016/0960-894X(96)00310-1
(1996)Doi:10.1039/c4ra02201g
(2014)Doi:10.1055/s-0035-1561952
(2016)Doi:10.3762/bjoc.10.129
(2014)Doi:10.1002/adsc.201400191
(2014)Doi:10.1002/anie.201405359
(2014)
