Efficient synthesis and versatile reactivity of porphyrinyl grignard reagents

DOI: 10.1002/ejoc.201402391

Source and publish data:

European Journal of Organic Chemistry p. 4327 - 4334 (2014)

Update date:2022-08-02

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Authors:

Fujimoto, Keisuke

Yorimitsu, Hideki

Osuka, Atsuhiro

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Article abstract of DOI:10.1002/ejoc.201402391

Iodine-magnesium exchange between iodoporphyrins and iPrMgCl·LiCl proceeded successfully without decomposition of the porphyrin core. The resulting porphyrinyl Grignard reagents are nucleophilic enough to react with various carbonyl compounds, such as ald

Full text of DOI:10.1002/ejoc.201402391

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