Stereoselective Syntheses of 3,3-difluoro-1-propene Derivatives

DOI: 10.1016/S0040-4039(00)60400-8

Source and publish data:

Tetrahedron Letters p. 7565 - 7566 (1993)

Update date:2022-08-04

Topics:

Authors:

Tellier, Frederique

Sauvetre, Raymond

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)60400-8

A highly regio- and stereo-selective introduction of a difluoromethylene group in allylic position is described.The key step is the treatment of 3-acetoxy-1,1-difluoro-1-propenes with Grignard reagents in the presence of copper and lithium salts.

Full text of DOI:10.1016/S0040-4039(00)60400-8

Products guided by the article

Product name:1-acetoxy-1-(1,1-difluorovinyl)cyclohexane

Cas No:163925-64-2

R&D Labs maybe for 163925-64-2

Changzhou Qidi Chemical Co., Ltd

website:http://www.czqdhg.com/

Contact:86-519-83382137

Address:128-1-16# HuaYuan Street,Hutang Town,Wujin District,Changzhou City,P.R.China.
Quhua Zhongxing Refrigeration Technology Co.,Ltd.

Contact:+86-5708886618

Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
jiangsu senxuan pharmaceutical and chemical co.,ltd

Contact:86-523-87982810

Address:hongqiao industrial zone,taixing,jiangsu china
Wuhan Shengmao Corp

website:http://www.shengmaochem.com

Contact:86-27-82853423, 82819281

Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China

Relevant to this article

Doi:10.1021/ja00817a032
(1974)
Base-catalyzed bicyclization of dialkyl glutaconates with cinnamoylacetamides: A synthetic strategy for isoquinolinedione derivatives

Doi:10.1039/c3cc46931j
(2014)
Asymmetric organocatalytic desymmetrization of 4,4-disubstituted cyclohexadienones at high pressure: A new powerful strategy for the synthesis of highly congested chiral cyclohexenones

Doi:10.1039/c4ob00733f
(2014)
Iron-catalyzed C(sp²)-H and C(sp³)-H arylation by triazole assistance

Doi:10.1002/anie.201311024
(2014)
Direct Alkenylation of 2-Methylquinolines with Aldehydes through Synergistic Catalysis of 1,3-Dimethylbarbituric Acid and HOAc

Doi:10.1002/adsc.201900351
(2019)
Doi:10.1007/BF00478078
()

Article Doi