Stereoselective Syntheses of 3,3-difluoro-1-propene Derivatives

DOI: 10.1016/S0040-4039(00)60400-8

Source and publish data:

Tetrahedron Letters p. 7565 - 7566 (1993)

Update date:2022-08-04

Topics:

Authors:

Tellier, Frederique

Sauvetre, Raymond

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)60400-8

A highly regio- and stereo-selective introduction of a difluoromethylene group in allylic position is described.The key step is the treatment of 3-acetoxy-1,1-difluoro-1-propenes with Grignard reagents in the presence of copper and lithium salts.

Full text of DOI:10.1016/S0040-4039(00)60400-8

Products guided by the article

Product name:1-acetoxy-1-(1,1-difluorovinyl)cyclohexane

Cas No:163925-64-2

R&D Labs maybe for 163925-64-2

Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
Career Henan Chemical Co

website:http://www.coreychem.com

Contact:+86-371-86658258

Address:Building 10 of Innovation Park, East District of the National University Science Park
Shanghai TBBMed Co.,Ltd

website:http://www.tbbmed.com

Contact:86--21-50498136

Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China

Relevant to this article

Doi:10.1021/ja00817a032
(1974)
Base-catalyzed bicyclization of dialkyl glutaconates with cinnamoylacetamides: A synthetic strategy for isoquinolinedione derivatives

Doi:10.1039/c3cc46931j
(2014)
Asymmetric organocatalytic desymmetrization of 4,4-disubstituted cyclohexadienones at high pressure: A new powerful strategy for the synthesis of highly congested chiral cyclohexenones

Doi:10.1039/c4ob00733f
(2014)
Iron-catalyzed C(sp²)-H and C(sp³)-H arylation by triazole assistance

Doi:10.1002/anie.201311024
(2014)
Direct Alkenylation of 2-Methylquinolines with Aldehydes through Synergistic Catalysis of 1,3-Dimethylbarbituric Acid and HOAc

Doi:10.1002/adsc.201900351
(2019)
Doi:10.1007/BF00478078
()

Article Doi