Anomalous deprotonation of tricarbonyl(η5-1-arylcyclohexadienyl)iron complexes

DOI: 10.1016/0022-328X(94)05269-H

Source and publish data:

Journal of Organometallic Chemistry p. C74 - C77 (1995)

Update date:2022-08-03

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Authors:

Malkov, Andrei V.

Stephenson, G. Richard

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Article abstract of DOI:10.1016/0022-328X(94)05269-H

1-Aryl substituted cyclohexadienyl complexes provide the first examples of deprotonation from C-6 of tricarbonyl(cyclohexadienyl)iron(1 + ) complexes, and, in the case of ortho-substituted aryl substituents, a reversed regiocontrol of nucleophile addition.Keywords: Iron; Carbonyl; Cyclohexadienyl; Biaryl; Deprotonation

Full text of DOI:10.1016/0022-328X(94)05269-H

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