trans-Hydroxotris(isothiocyanato)bis-(triphenylphosphine)rhenium(IV) Methanol Solvate

DOI: 10.1107/S0108270194008498

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 876 - 878 (1995)

Update date:2022-08-02

Topics:

Authors:

Huebener, Rainer

Abram, Ulrich

Straehle, Joachim

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Article abstract of DOI:10.1107/S0108270194008498

The title compound consists of well-separated units of complexes and MeOH solvent molecules.The Re atom is six-coordinate in a distorted octahedral coordination sphere.The two triphenylphosphine ligands are arranged trans to each other.The Re-OH distances is 2.171 (4) Angstroem and lies in the range for a single Re-O bond.The NCS ligands are coordinated via nitrogen.

Full text of DOI:10.1107/S0108270194008498

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