Unexpected formation of the new oxorhenium(V) complex [ReO(NH(CH2CH2S)2) (SC6H5)] obtained by N-C cleavage of the tripodal ligand N(CH2CH2SH)3

DOI: 10.1016/S0020-1693(96)05461-8

Source and publish data:

Inorganica Chimica Acta p. 143 - 147 (1997)

Update date:2022-07-31

Topics:

Authors:

Glaser Glaser

Spies Spies

Berger Berger

Hahn Hahn

Luegger Luegger

Johannsen

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Article abstract of DOI:10.1016/S0020-1693(96)05461-8

The tripodal ligand 2,2′,2″-nitrilotris(ethanethiol) (N(SH)₃ = N(CH₂CH₂SH)₃) reacts with [ReO(SC₆H₅)₄]^- as rhenium(V) precursor to give unexpectedly the square-pyramid

Full text of DOI:10.1016/S0020-1693(96)05461-8

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Product name:ReO(HN(CH₂CH₂S)2)(SC₆H₅)

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