Journal of Organic Chemistry p. 5347 - 5357 (1994)
Update date:2022-09-26
Topics: Synthesis Cyclization Functionalized Azomethine Ylides Bonds
Padwa, Albert
Dean, Dennis C.
Osterhout, Martin H.
Precedo, Laura
Semones, Mark A.
α-Diazo carbonyl compounds containing an imino group in the γ-position have been found to undergo a rhodium(II) acetate induced cyclization reaction to generate cyclic azomethine ylides.The reactive dipole undergoes a subsequent 1,3-dipolar cycloaddition
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