Reaction of OsHCl(CO)(PiPr3)2 with cyclohexylacetylene: Formation of a hydrido-vinylidene complex via a 1,3-hydrogen shift

DOI: 10.1021/om00007a074

Source and publish data:

Organometallics p. 3596 - 3599 (1995)

Update date:2022-09-26

Topics:

Authors:

Esteruelas, Miguel A.

Oro, Luis A.

Valero, Cristina

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00007a074

The complex OsHCl(CO)(PiPr₃)₂ (1) reacts with cyclohexylacetylene to give OsHCl(=C=CHCy)(CO)-(PiPr₃)₂ (2), which evolves in solution to OsCl{(E)-CH=CHCy}(CO)(PiPr₃)₂ (3). Complex 3 reacts w

Full text of DOI:10.1021/om00007a074

Products guided by the article

Product name:Os(P(CH(CH₃)2)3)2(CO)(Cl)(CHCHC₆H₁₁)

Cas No:166832-36-6

R&D Labs maybe for 166832-36-6

Shandong Green Bio-Pharmaceutical Co.,Ltd

Contact:+86-530-5408622

Address:High-tech Development Zone, Heze City, Shandong, China
Chengdu Boon Stream Chemical Industry Co.,Ltd.

Contact:+86-28-83156758

Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
SuZhou Ascepion Pharmaceuticals, Inc.(expird)

Contact:0512-86881668

Address:Building C,68Xingqing Road,Suzhou,China.
jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road

Relevant to this article

Doi:10.1021/ja01490a071
(1960)
Novel thiosemicarbazide derivatives with 4-nitrophenyl group as multi-target drugs: α-glucosidase inhibitors with antibacterial and antiproliferative activity

Doi:10.1016/j.biopha.2017.07.049
(2017)
Unusual transformation of the 3-hydroxy-picolinoyl residue of pristinamycin I(A)

Doi:10.7164/antibiotics.48.676
(1995)
Iron-Catalyzed Cleavage Reaction of Keto Acids with Aliphatic Aldehydes for the Synthesis of Ketones and Ketone Esters

Doi:10.1002/chem.202000114
(2020)
Synthesis of 'retro-inverso' peptide nucleic acids: 1. Characterization of the monomers

Doi:10.1016/0040-4039(95)01374-Q
(1995)
Doi:10.1246/bcsj.40.1933
(1967)

Article Doi