Reaction of OsHCl(CO)(PiPr3)2 with cyclohexylacetylene: Formation of a hydrido-vinylidene complex via a 1,3-hydrogen shift

DOI: 10.1021/om00007a074

Source and publish data:

Organometallics p. 3596 - 3599 (1995)

Update date:2022-09-26

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Authors:

Esteruelas, Miguel A.

Oro, Luis A.

Valero, Cristina

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Article abstract of DOI:10.1021/om00007a074

The complex OsHCl(CO)(PiPr₃)₂ (1) reacts with cyclohexylacetylene to give OsHCl(=C=CHCy)(CO)-(PiPr₃)₂ (2), which evolves in solution to OsCl{(E)-CH=CHCy}(CO)(PiPr₃)₂ (3). Complex 3 reacts w

Full text of DOI:10.1021/om00007a074

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Product name:Os(P(CH(CH₃)2)3)2(CO)(Cl)(CHCHC₆H₁₁)

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