Cationic vinylidene-bridged complexes and their reactions with alkynes to yield either alkyne- and vinylidene-bridged or bis(vinylidene) products. Facile interconversion between terminal and bridging vinylidene bonding modes

DOI: 10.1021/om00006a054

Source and publish data:

Organometallics p. 3040 - 3057 (1995)

Update date:2022-08-04

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Authors:

Wang, Li-Sheng

Cowie, Martin

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Article abstract of DOI:10.1021/om00006a054

Reaction of the cationic A-frame complex [Ir₂(CO)₂(μ-I)(dPPm)₂)][SO ₃CF₃] (2) (dppm = Ph₂-PCH₂PPh₂) with either acetylene or phenylacetylene at -78°C yields the respec

Full text of DOI:10.1021/om00006a054

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Product name:Ir₂(CO)2(C₂H₂)I(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*CF₃SO₃^(1-)=[Ir₂(CO)2(C₂H₂)I(((C₆H₅)2P)2CH₂)2]OSO₂CF₃

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