Synthesis of Medium-Membered Heterocyclic Allenes by Sigmatroic Rearrangement and Its Synthetic Application to the Antifungal Constituent of Sapium Japonicum

DOI: 10.1016/0040-4039(94)88037-9

Source and publish data:

Tetrahedron Letters p. 1255 - 1258 (1994)

Update date:2022-08-03

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Authors:

Harusawa, Shinya

Kase, Naoki

Yoneda, Ryuji

Kurihara, Takushi

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Article abstract of DOI:10.1016/0040-4039(94)88037-9

Medium-membered heterocyclic allenes were synthesized by the <3,3>sigmatropic rearrangement of cyclic thionocarbonates.Using this methodology and a novel application of a SmI2-HMMPA reduction, an antifungal constituent of Sapium Japonicum, methyl 8-hydrox

Full text of DOI:10.1016/0040-4039(94)88037-9

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