Utility of Mixed-Ligand Alkylaluminum Reagents in the Formation of Mixed-Metal Yttrium and Lanthanide Aluminum Compounds

DOI: 10.1021/ic00115a039

Source and publish data:

Inorganic Chemistry p. 3079 - 3082 (1995)

Update date:2022-08-04

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Authors:

Evans, William J.

Ansari, Mohammad A.

Ziller, Joseph W.

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Article abstract of DOI:10.1021/ic00115a039

[(ArO)2(THF)Y(μ-OAr)]2 (Ar = C6H3Me2-2,6) reacts with Al2Me6, or AlEt3 in toluene or hexanes to form the mixed-metal products (ArO)2(THF)2Y(μ-OAr)2AlR2 [R - Me (1), Et (2)]. These complexes can be obtained in quantitative yield from [AlR2(OAr)]2 and Y(OAr

Full text of DOI:10.1021/ic00115a039

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Product name:(2,6-dimethylphenoxide)2(tetrahydrofuran)2Y(μ-2,6-dimethylphenoxide)2AlMe2

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