Isothiocyanato Complexes of Rhenium. V. trans-Bis(isothiocyanato)(methoxy)(phenylimido)bis(triphenylphosphine)rhenium(V)

Article abstract of DOI:10.1107/S0108270195000564

The title compound consists of well separated molecules of .The Re atom is six-coordinate in a distorted octahedral environment.The two triphenylphosphine ligands are arranged trans to each other and there is a methoxy group in the position trans to the phenylimido group.The Re-NPh distance is 1.744(4) Angstroem and the NCS ligands are coordinated via the N atom.