Intramolecular Olefinic Aldehyde Prins Reactions for the Construction of Five-Membered Rings

DOI: 10.1021/jo00221a034

Source and publish data:

Journal of Organic Chemistry p. 4144 - 4151 (1985)

Update date:2022-07-29

Topics:

Authors:

Andersen, Niels H.

Hadley, Stephen W.

Kelly, James D.

Bacon, E. R.

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Article abstract of DOI:10.1021/jo00221a034

Four catalysts (Me2AlCl <*> SnCl4 > EtAlCl2 > Et2AlCl) for the cyclization of olefinic aldehydes by an internal Prins mechanism have been compared by using systems that afford five-membered rings by type I and type II ene processes.Stannic chloride and Me

Full text of DOI:10.1021/jo00221a034

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