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Journal of Materials Chemistry A
Page 4 of 4
DOI: 10.1039/C8TA00341F
COMMUNICATION
Journal Name
ꢀꢁ
ꢂꢁ
ꢃ
ꢀꢁ
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=
+
, where qe is the equilibrium adsorption capacity
ꢂꢄꢅꢆꢇꢈ
ꢂꢄꢅꢆ
of aniline; Ce is the equilibrium concentration of aniline in the 17. W. Lu, D. Yuan, J. Sculley, D. Zhao, R. Krishna and H. Zhou, J. Am. Chem.
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solution; qmax is the monolayer adsorption capacity; and KL is the
equilibrium constant of Langmuir adsorption model (see ESI).
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mg.g-1)47
, ,
sawdust-β-CD polymer (SD-β-CD, 84.00 mg.g-1)52
molecular imprinted polymers (MIPs, 0.76 mg.g-1)48
carbon nitride (g-C3N4, 93.40 mg.g-1)49, and manganese oxide-
modified diatomite (Mn-D, 42.90 mg.g-1)50
, Graphitic
.
In addition, the adsorption of aniline onto the Azo-POP-1 was
exothermic base on fact that the adsorption capacity decreased
along with the temperature increased. The strong adsorption ability
of Azo-POP-1 towards aniline, could be a result of the hydrophobic
π-π interactions and the potential hydrogen bond interaction
between aniline and Azo-POP-1.
In summary, this paper reported a time-efficient and robust
preparation of Azo-POPs by reductive coupling polymerization on
nitro-containing monomers. The as-prepared Azo-POPs were found
to have high BET SA and be good candidates as absorbent materials
towards aniline in water. The preparation of more Azo-POPs by our
methodology and further applications in removal of organic
pollutants from water is now undergoing in our lab. The relevant
results will be reported in due course.
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There are no conflicts of interest to declare.
Acknowledgements
The authors thank the National Natural Science Foundation of China
(No. 21772013 and 21202008), Beijing Natural Science Foundation
(No. 2162039) and the Fundamental Research Funds for the Central
Universities for generous support.
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