Divergent and stereocontrolled approach to the synthesis of uracil nucleosides branched at the anomeric position

DOI: 10.1021/jo00108a031

Source and publish data:

Journal of Organic Chemistry p. 656 - 662 (1995)

Update date:2022-08-04

Topics:

Authors:

Itoh Itoh

Haraguchi

Tanaka Tanaka

Gen Gen

Miyasaka

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Article abstract of DOI:10.1021/jo00108a031

Electrophilic addition of NBS/pivalic acid (bromopivaloyloxylation) to 1-[3,5-bis-O-(tert-butyldimethylsilyl)-2-deoxy-D-erythro-pent-1-enofur anosyl]uracil (2), readily accessible from O²,2'-anhydrouridine, furnished 1-[2-bromo-3,5-bis-O-(tert-

Full text of DOI:10.1021/jo00108a031

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Product name:1'-C-Allyl-3',5'-di-O-benzoyl-O²,2'-anhydrouridine

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