Chemistry of Insect Antifeedants from Azadirachta Indica (Part 19): A Potential Relay Route for the Synthesis of Azadirachtin.

DOI: 10.1016/0040-4020(95)00297-L

Source and publish data:

Tetrahedron p. 6591 - 6604 (1995)

Update date:2022-08-04

Topics:

Authors:

Denholm, Alastair A.

Jennens, Lyn

Ley, Steven V.

Wood, Anthony

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Article abstract of DOI:10.1016/0040-4020(95)00297-L

A potential relay route for the synthesis of azadirachtin (1) has been established.An advanced intermediate 4 has been prepared and methods to convert this back to the natural product has been developed, in particular, the reintroduction of the enol double bond using an acetal exchange process.

Full text of DOI:10.1016/0040-4020(95)00297-L

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