Samarium(II) iodide promoted reductive ring opening reaction of cyclopropane-1,1-dicarboxylic esters. Synthesis of substituted 5-Pentanolides from carbonyl compounds and dimethyl cyclopropane-1,1-dicarboxylate

DOI: 10.1016/0040-4039(94)80123-1

Source and publish data:

Tetrahedron Letters p. 7805 - 7808 (1994)

Update date:2022-08-04

Topics:

Authors:

Imamoto, Tsuneo

Hatajima, Toshihiko

Yoshizawa, Takeshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)80123-1

Dimethyl cyclopropane-1,1-dicarboxylate is readily subjected to reductive ring opening reaction with samarium(II) iodide in the presence of tris(dibenzoyl-methiodo)iron(III). The generated organosamarium intermediate is trapped by aliphatic ketones to aff

Full text of DOI:10.1016/0040-4039(94)80123-1

Products guided by the article

Product name:S,S'-diphenyl 2-ethyldithiomalonate

Cas No:16855-58-6

R&D Labs maybe for 16855-58-6

Hubei anhuang chemical Co.Ltd

Contact:

Address:308# dongwu avenue dongxihu district wuhan city
Zhongshan Haihong Medicine Co., Ltd.

Contact:86-0760-86925778 （0）18824993998

Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China

Relevant to this article

Optically Active Bicyclo<2.2.2>octane Derivatives; Synthesis of (1S,4R,6R)-6-Hydroxybicyclo<2.2.2>octan-2-one from Its Enantiomer

Doi:10.1016/0957-4166(95)00105-X
(1995)
Synthesis and characterization of sterically hindered diarylsilanes containing 2,4,6-trimethylphenyl and 2,4,6-tris( trifluoromethyl) phenyl substituents. X-ray crystal structure of bis<2,4,6-tris( trifluoromethylphenyl)>fluorosilane

Doi:10.1016/0022-328X(95)00327-M
(1995)
The Synthesis of Molecular Docking Studies, In Vitro Antimicrobial and Antifungal Activities of Novel Dipeptide Derivatives Based on N-(2-(2-Hydrazinyl-2-oxoethylamino)-2-oxoethyl)-nicotinamide

Doi:10.3390/molecules23040761
(2018)
Thermal rearrangement of enantioenriched α-hydroxy imines -I. Enantiocontrolled synthesis of α-substituted α-amino ketones

Doi:10.1016/0040-4039(95)00680-B
(1995)
Highly diastereoselective additions of methoxyallene and acetylenes to chiral α-keto amides

Doi:10.1039/b100355k
(2001)
Design, synthesis, and in vitro activities of benzamide-core glycoprotein IIb/IIIa antagonists: 2,3-Diaminopropionic acid derivatives as surrogates of aspartic acid

Doi:10.1016/S0968-0896(97)00013-8
(1997)

Article Doi