Uebergangsmetall-substituierte Diphosphene. XXXVI. Cyclopropanierung der P=P-Bindung in den -Cycloaddukten aus Metallodiphosphenen und Hexafluoroaceton, (M = Fe; R5 = Me4Et) (M = Ru; R5 = Me5)

DOI: 10.1016/0022-328X(95)05436-S

Source and publish data:

Journal of Organometallic Chemistry p. 127 - 130 (1995)

Update date:2022-08-03

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Authors:

Weber, Lothar

Misiak, Hanns

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Article abstract of DOI:10.1016/0022-328X(95)05436-S

The <3+2> cycloadducts (M = Fe, R5 = Me4Et (IIIb)) (M = Ru; R5 = Me5 (IVa)) and diazomethane undergo a <2+1>-cycloaddition at the P=P bond to afford the spiro compounds (VII and VIII).Keywords: Metallodiphosphene; Hexafluoroacetone adducts; Diazomethane

Full text of DOI:10.1016/0022-328X(95)05436-S

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